{"product_id":"marc-visseaux-catalysts-for-the-controlled-polymerization-of-conjugated-dienes-9783039361908","title":"Catalysts for the Controlled Polymerization of Conjugated Dienes","description":"Since the beginning of the 1960s, the coordinative polymerization of conjugated dienes has continuously improved. Today, chemists know how to polymerize conjugated dienes stereospecifically and in a controlled fashion, both petro-sourced (nowadays also bio-sourced) and those of natural origin. The industry has greatly improved the performances of the catalytic systems-covering a wide range of elements including metals from groups 4-6 and 8-10, and rare earths-with the aim of optimizing the preparation of synthetic polymers for a large range of industrial applications. Nowadays, there is a better understanding of the polymerization mechanism involving allyl-active species, thanks in particular to the support of more efficient calculation methods. In addition, statistical copolymerization of 1,3-dienes with olefin or styrene comonomers and innovative approaches to coordinative chain transfer polymerization allow the production of copolymers with controlled topology, while a last challenge is about to be solved with the preparation of stereoregular polydienes that are also end-functionalized. This issue brings together several important aspects of this chemistry that remain at the forefront of both academic and industrial research.","brand":"MDPI AG","offers":[{"title":"Default Title","offer_id":53701882020182,"sku":null,"price":0.0,"currency_code":"EUR","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0925\/5829\/5382\/files\/product_image_9783039361908_1_5da651d1-a680-4d8b-a2d6-e2a3cd8fb05c.jpg?v=1781757802","url":"https:\/\/www.momoxbooks.com\/products\/marc-visseaux-catalysts-for-the-controlled-polymerization-of-conjugated-dienes-9783039361908","provider":"momoxbooks","version":"1.0","type":"link"}