{"product_id":"barman-souvik-catecholase-activity-study-in-metal-vs-metal-free-condition-9786208455866","title":"Catecholase Activity Study in Metal vs. Metal Free Condition","description":"Transition metal complexes as catalysts and, occasionally, basic pH as a reaction condition were employed to imitate the catecholase activity. Using Morpholine\/Piperazine as a catalyst, under photo-mediated condition the catalytic aerobic oxidation of the proxy substrate 3,5-di-tert-butylcatechol (DTBC) in methanol very fast was shown in this article to be a functional mimic of catecholase activity. The Michaelis-Menten kinetic model's enzymatic substrate inhibition pattern was used to describe the kinetic manifestation of DTBC oxidation. Under photo-mediated condition the oxidation of DTBC was observed very fast which may be due to the higher energy increases the activation energy and under basic condition catechol oxidizes to o-quinone (DTBQ).","brand":"LAP LAMBERT Academic Publishing","offers":[{"title":"Default Title","offer_id":53631263899990,"sku":null,"price":0.0,"currency_code":"EUR","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0925\/5829\/5382\/files\/product_image_9786208455866_1.jpg?v=1778696547","url":"https:\/\/www.momoxbooks.com\/products\/barman-souvik-catecholase-activity-study-in-metal-vs-metal-free-condition-9786208455866","provider":"momoxbooks","version":"1.0","type":"link"}